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Antiperiplanar

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Mar 7, 2018
6:47

Chem 240 Videos - Video 37 Updated (with better sound! Better production values! Chem3D images!) version is HERE: https://youtu.be/KxjjbX7Susc The key orbital alignment in an E2 elimination is "anti-periplanar". The Leaving group is aligned with, but opposite the H that is abstracted. This is to ensure good overlap between C-H sigma and C-LG sigma star orbitals... ...but it also has implications for geometry and regioisomerism that are best illustrated in 6-membered ring systems or via newman projections, as illustrated.

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Antiperiplanar | NatokHD