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Kinetics : two parallel reactions derivation

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Mar 28, 2021
9:18

00:18 Introduction 00:35 Reaction scheme 01:06 Rate of change of [X] 01:45 Let 𝘬 = π˜¬β‚ + π˜¬β‚‚ 02:06 Separate variables 𝘡, and [X] 02:24 Integrate each side from time 𝘡 = 0 until 𝘡 02:50 Solve each integral 03:06 Raise each side as a power of e, apply properties of logarithm 03:27 Rate of change of [Y] 03:43 Substitute expression at 03:06 into one at 03:27 04:07 Multiply each side of equation by π˜₯𝘡 04:43 Integrate each side, applying the boundary conditions 05:18 Multiply right side by -1 and switch limits of integration 05:53 Expression for [Y] at any time 𝘡 greater than 0 06:18 Rate of change of [Z] 07:12 Integrate each side, applying the boundary conditions 07:39 Multiply right side by -1 and switch limits of integration 08:01 Side-by-side comparison of expressions for [Y] and [Z] 08:22 Take ratio of [Y] to [Z] 08:48 Final result for 𝘡 greater than 0, and π˜¬β‚‚ β‰  0 Step-by-step, color-coded derivation for the ratio of the products (Y, Z) of two parallel, first order reactions that proceed either in one way from X to Y with rate constant π˜¬β‚, or in one way from X to Z with rate constant π˜¬β‚‚. Derivation assumes π˜¬β‚‚ β‰  0, and that initial concentrations of Y and Z are exactly 0. Derived ratio will then be valid for any time after π˜΅β‚€ = 0. Don't forget to like, comment, share, and subscribe!

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Kinetics : two parallel reactions derivation | NatokHD