00:18 Introduction
00:35 Reaction scheme
01:06 Rate of change of [X]
01:45 Let π¬ = π¬β + π¬β
02:06 Separate variables π΅, and [X]
02:24 Integrate each side from time π΅ = 0 until π΅
02:50 Solve each integral
03:06 Raise each side as a power of e, apply properties of logarithm
03:27 Rate of change of [Y]
03:43 Substitute expression at 03:06 into one at 03:27
04:07 Multiply each side of equation by π₯π΅
04:43 Integrate each side, applying the boundary conditions
05:18 Multiply right side by -1 and switch limits of integration
05:53 Expression for [Y] at any time π΅ greater than 0
06:18 Rate of change of [Z]
07:12 Integrate each side, applying the boundary conditions
07:39 Multiply right side by -1 and switch limits of integration
08:01 Side-by-side comparison of expressions for [Y] and [Z]
08:22 Take ratio of [Y] to [Z]
08:48 Final result for π΅ greater than 0, and π¬β β 0
Step-by-step, color-coded derivation for the ratio of the products (Y, Z) of two parallel, first order reactions that proceed either in one way from X to Y with rate constant π¬β, or in one way from X to Z with rate constant π¬β.
Derivation assumes π¬β β 0, and that initial concentrations of Y and Z are exactly 0. Derived ratio will then be valid for any time after π΅β = 0.
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