This video tutorial goes through the steps of creating custom glass materials in V-Ray for Rhino. This includes a basic glass material, coloured glass, frosted glass and textured glass. I have included the timestamps below if you want to skip ahead to any key sections in the video:
1:43 - Setting up a generic material
2:03 - Basic diffuse, reflection and refraction settings
3:00 - Refraction adjustments
3:40 - Reflection adjustments - increasing the reflection amount but retaining the transparency
4:35 - Coloured glass material
6:00 - Frosted and opaque glass effect
7:10 - Applying maps to control how the glossiness of the glass (frosted glass gradients)
9:46 - Adding texture to the glass material (fluted glass)
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Glass Material Creation - V-Ray for Rhino - Tutorial | NatokHD