This video tutorial goes through the steps of creating custom metal materials in V-Ray for Rhino. I have included the timestamps below so you can skip ahead to any specific sections:
0:50 - Creating the base metal material
1:25 - Reflection settings and fresnel reflections
2:57 - Coloured metals, gold or bronze
3:40 - Adding rounded/ chamfered edges to the geometry using the material
5:20 - Adding a dirt map to the reflection glossiness and the bump map to add imperfections
The imperfection map for the gold texture was acquired from here:
https://www.textures.com/download/pbr0837/139492
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Metal Material Creation - V-Ray for Rhino - Tutorial | NatokHD